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Catalytic dimerization of ethylene to 1-butene by square-planar nickel complexes

✍ Scribed by R. Ceder; G. Muller; J. Sales; J. Vidal; D. Neibecker; I. Tkatchenko


Publisher
Elsevier Science
Year
1991
Weight
629 KB
Volume
68
Category
Article
ISSN
0304-5102

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The novel nickel(II)-and palladium(II) complexes (box)Ni(acac) 2 (1), (box)Ni(mes)(Br) (2), (box)Pd(mes) 2 (3), [(PEMA)NiBr]Br (4 a) and [(PEMA)PdCl]Cl (4 b) were synthesized and investigated by IR-, MS-and (except the paramagnetic compound 1) by NMR spectroscopy (box: 4,4,4',4'-tetramethyl-2,2'-bis