✦ LIBER ✦

Catalytic deoxygenation of organic compounds by carbon monoxide: III. The reaction under pressure of aromatic nitro compounds in the presence of o-phthalaldehyde

✍ Scribed by Abul F. M. Iqbal

Publisher: John Wiley and Sons
Year: 1972
Tongue: German
Weight: 406 KB
Volume: 55
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19720550308

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reaction of o‐phthalaldehyde with several aromatic nitro compounds in the presence of carbon monoxide and catalytic quantities of hexarhodium‐hexadecacarbonyl eventuated in the formation of the corresponding N‐substituted isoindolinone as the major product. A reaction mechanism has been suggested incorporating deoxygenation of the nitro compound by carbon monoxide to a nitrene intermediate and the subsequent interception of the latter by o‐phthalaldehyde.

📜 SIMILAR VOLUMES

The Catalytic Deoxygenation of Aromatic

The Catalytic Deoxygenation of Aromatic Nitro Compounds by Carbon Monoxide in the Presence of Diphenylacetylene

✍ Dr. Abul F. M. Iqbal 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 189 KB 👁 1 views

ChemInform Abstract: Reduction of Aromat

ChemInform Abstract: Reduction of Aromatic Nitro Compounds Using Samarium Metal in the Presence of a Catalytic Amount of Iodine under Aqueous Media.

✍ Lei Wang; Longhu Zhou; Yongmin Zhang 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

Selenium-Catalyzed Reduction of Aromatic

Selenium-Catalyzed Reduction of Aromatic Nitro Compounds to Amines by CO/H2O in the Presence of Triethylamine

✍ Toshiyuki Miyata; Dr. Kiyoshi Kondo; Prof. Dr. Shinji Murai; Dr. Tsuneaki Hirash 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB 👁 2 views

Catalytic Aminomethylation of Alkenoic C

Catalytic Aminomethylation of Alkenoic Compounds: I. Reaction of monoolefins with secondary amines, carbon monoxide, and water in the presence of rhodium and iron catalysts

✍ Abul F. M. Iqbal 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 German ⚖ 387 KB