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Catalytic dehydrogenation of isopropyl alcohol

โœ Scribed by J.S.H.


Publisher
Elsevier Science
Year
1930
Tongue
English
Weight
55 KB
Volume
210
Category
Article
ISSN
0016-0032

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โœฆ Synopsis


57o-571) have removed hydrogen from isopropyl alcohol and thereby produced acetone by passing the vapor of the alcohol through an iron furnace which is kept at a temperature of 400' C. and is charged with crucible graphite, made from crystalline Ceylon graphite baked with clay and broken to g-mesh size.

The yield is practically quantitative.


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โœ G.B.W.L. Ligthart; R.H. Meijer; M.P.J. Donners; J. Meuldijk; J.A.J.M. Vekemans; ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 61 KB

The catalytic dehydrogenation of alcohols into aldehydes and ketones in the absence of H-acceptors was studied with several transition metal catalysts in order to develop a large-scale procedure. Applying Ru(OCOCF 3 ) 2 (CO)(PPh 3 ) 2 , the so called Robinson catalyst, several secondary alcohols cou