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Catalytic dehydrogenation of ethylbenzene and tetrahydrofuran by a dihydrido iridium P–C–P pincer complex

✍ Scribed by Gupta, Mukta; Kaska, William C.; Jensen, Craig M.


Book ID
121078280
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
31 KB
Volume
5
Category
Article
ISSN
1359-7345

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Density functional studies of catalytic
✍ Hua-Jun Fan; Michael B. Hall 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 177 KB

Density functional calculations have been applied to models of both transfer and acceptorless alkane dehydrogenation for the iridium(III) pincer complex, ( R PCP)IrH 2 ( R PCP= 3 -C 6 H 3 (CH 2 PR 2 ) 2 -1,3). The iridium pincer complex is the first efficient homogeneous catalyst that does not requi