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Catalytic dehydration of alcohols by OH. (H3C)3CCH2OH: A limiting case

โœ Scribed by Frank P. Tully

Book ID
108392592
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
460 KB
Volume
23
Category
Article
ISSN
1540-7489

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The azide opening reaction of trans-2,3-epoxy alcohols with NaN 3 and PhB(OH) 2 in DMF occurred regio-and stereoselectively at the C-2 position giving rise to phenylboronates of trans-2-azido-1,3-diols in high yields, o 1999 Elsevier Science Ltd. All rights reserved. Stereoselective epoxide-opening