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Catalytic Cyclopropanation of Fluorine-Containing Alkenes and Dienes with Diazomethane and Methyl Diazoacetate.

✍ Scribed by Ekaterina V. Guseva; Nikolay V. Volchkov; Yury V. Tomilov; Oleg M. Nefedov


Book ID
101962718
Publisher
John Wiley and Sons
Year
2004
Weight
40 KB
Volume
35
Category
Article
ISSN
0931-7597

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Catalytic Cyclopropanation of Fluorine-C
✍ EkaterinaΒ V. Guseva; NikolayΒ V. Volchkov; YuryΒ V. Tomilov; OlegΒ M. Nefedov πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 167 KB

## Abstract The reactivities of various double bonds in fluorine‐containing unsaturated compounds toward cyclopropanation with diazomethane and methyl diazoacetate with catalysis by copper, rhodium and palladium compounds were studied. In general, the presence of fluorine atoms attached to the doub