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Catalytic Conversion of Aldehydes into Higher α-Siloxy Aldehydes by Hydrosilane and Carbon Monoxide

✍ Scribed by Prof. Dr. Shinji Murai; Toshikazu Kato; Prof. Dr. Noboru Sonoda; Dr. Yoshio Seki; Prof. Dr. Kazuaki Kawamoto

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 263 KB
Volume: 18
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.197903931

No coin nor oath required. For personal study only.

✦ Synopsis

C 0 MMUN ICATIONS gave rr-[diethyl(methyl)siloxy]octanal ( 2 b ) in 50 % yieldL4'. Similar results were obtained with butanal (1 a ) and cyclohexanecarboxaldehyde ( I cjE4] (yields 49 and 54 %, respectively).

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