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Catalytic codimerization of styrene and various acetylenic compounds to 1,3-dienes using palladium halide-lithium halide system

✍ Scribed by Kiyotomi Kaneda; Tetsuya Uchiyama; Hiroya Kobayashi; Yuzo Fujiwara; Toshinobu Imanaka; Shiichiro Teranishi

Book ID: 104235962
Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 194 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83665-0

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✦ Synopsis

Recently we reported catalytic cooliqomerization of acetylenes and ally1 halides with palladium complexes under mild conditions.

1 We have proposed a "Pa-halogen bond recycle mechanism" which contains the addition of Pa-halogen bond to acetylene, followed by the insertion of ally1 halide and D-halogen

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