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Catalytic behaviors of magnesia-supported polytitanazane–platinum complex on the oxygenation of 3-heptanol

✍ Scribed by Xiao-Tun Yang; Jie Zheng; Mei-Yu Huang; Ying-Yan Jiang

Book ID
101290140
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
185 KB
Volume
7
Category
Article
ISSN
1042-7147

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✦ Synopsis

A kind of inorganic polymer-platinum complex, magnesia-supported polytitanazane-platinum complex (MgO-Ti-N-Pt), was prepared and used to catlayze the oxygenation of 3-heptanol. It was found that this kind of catalyst was very active and stable in the reaction. The objective product (3-heptanone) was obtained near 100% yield in 40 hr under moderate reaction temperature and atmospheric oxygen pressure.

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Preparation and characterization of silica- and magnesia-supported poly(3-aminopropylsiloxane)-platinum complexes and their catalytic activity in the oxidation of cyclohexanol and cyclopentanol with molecular oxygen
✍ Cheng-Guo Jia; Fu-Yan Liang; Liang-Jie Tang; Mei-Yu Huang; Ying-Yan Jiang 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 801 KB

## Abstract We have prepared silica‐ and magnesia‐supported poly(3‐aminopropylsiloxane)‐platinum complexes (abbreviated as SiO~2~‐PAPSPt and MgO‐PAPSPt, respectively) in which mixed valent platinum is coordinated by amino groups and aggregated to a certain extent. MgO‐PAPSPt contains low‐valent, ve