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Catalytic behavior of a Wool–Pd complex in asymmetric hydrogenation of diacetone alcohol and 3-methyl-2-butanone

✍ Scribed by Mao-Ya Yin; Guo-Li Yuan; Mei-Yu Huang; Ying-Yan Jiang


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
82 KB
Volume
147
Category
Article
ISSN
1381-1169

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Catalytic behavior of wool–Pt complex in
✍ Guo-Li Yuan; Mao-Ya Yin; Mei-Yu Huang; Ying-Yan Jiang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 2 views

A wool±Pt complex was prepared by the reaction of wool with chloroplatinic acid in ethanol solution, and was found to be useful as a chiral catalyst for the asymmetric hydrogenation of some ketones to corresponding chiral alcohols, such as 3-methyl-2-butanone to (R)-3-methyl-2-butanol, 4-methyl-2-pe