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Catalytic Beckmann rearrangement of ketoximes in ionic liquids

✍ Scribed by Jiajian Peng; Youquan Deng

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
54 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Under mild conditions and without any additional organic solvents, Beckmann rearrangements of several ketoximes were performed in the catalytic media consisting of room temperature ionic liquid based on 1,3-dialkylimidazolium or alkylpyridinium salts and phosphorated compounds. Excellent conversion and selectivity was achieved for cyclohexanone oxime as the substrate, while Beckmann fragmentation of cyclopentanone oxime was observed.

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