𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic, Asymmetric α-Chlorination of Acid Halides.

✍ Scribed by Stefan France; Harald Wack; Andrew E. Taggi; Ahmed M. Hafez; Ty R. Wagerle; Meha H. Shah; Crystal L. Dusich; Thomas Lectka


Publisher
John Wiley and Sons
Year
2004
Weight
251 KB
Volume
35
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


📜 SIMILAR VOLUMES


Catalytic Asymmetric Bromination and Chl
✍ Mauro Marigo; Nagaswami Kumaragurubaran; Karl Anker Jørgensen 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB 👁 1 views

## Abstract The first general catalytic asymmetric bromination and chlorination of β‐ketoesters has been developed. The reactions proceed for both acyclic and cyclic β‐ketoesters catalyzed by chiral bisoxazolinecopper(II) complexes giving the corresponding optically active α‐bromo‐ and α‐chloro‐β‐k

Acid catalytic effects in the chlorinati
✍ Tapio Salmi; Päivi Mäki-Arvela; Erkki Paatero; Rune Byggningsbacka 📂 Article 📅 2000 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 148 KB

Selective a-chlorination of propanoic acid to form 2-monochloropropanoic (MCA) and 2,2dichloropropanoic acid (DCA) was investigated in a laboratory-scale, semibatch reactor at 90±130 °C at atmospheric total pressure and in the presence of chlorosulfonic acid (ClSO 3 H) and 2,2dichloroethanoic acid (