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Catalytic asymmetric synthesis of optically active 2-alkanols via hydrosilylation of 1-alkenes with a chiral monophosphine-palladium catalyst

โœ Scribed by Uozumi, Yasuhiro; Hayashi, Tamio


Book ID
118055076
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
318 KB
Volume
113
Category
Article
ISSN
0002-7863

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Asymmetric synthesis catalyzed by chiral
โœ Hayashi, Tamio.; Hayashizaki, Keiichi.; Kiyoi, Takao.; Ito, Yoshihiko. ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 606 KB

averaged. The concentration of the free amide remaining after complexation could then be calculated from the extinction coefficient and used to determine the apparent equilibrium constant. The equilibrium between free amide and the sec-butyllithium-amide complex was established within less than ca.