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Catalytic Asymmetric Synthesis of Cyclic α-Allylated α-Fluoroketones.

✍ Scribed by E. C. Burger; B. R. Barron; J. A. Tunge


Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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Photoreduction of Cyclic α-Fluoroketones
✍ Karin Reinholdt; Paul Margaretha 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 287 KB

## Abstract Irradiation of the α‐fluoroketones **1a** and **6a** in i‐PrOH selectively affords the parent ketone **1b** and **6b**, respectively. It is concluded that in this solvent heterolytic C‐F bond cleavage of the anion radical‐formed by electron transfer to the excited fluoroketone‐is a fast