Photoreduction of Cyclic α-Fluoroketones
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Karin Reinholdt; Paul Margaretha
📂
Article
📅
1983
🏛
John Wiley and Sons
🌐
German
⚖ 287 KB
## Abstract Irradiation of the α‐fluoroketones **1a** and **6a** in i‐PrOH selectively affords the parent ketone **1b** and **6b**, respectively. It is concluded that in this solvent heterolytic C‐F bond cleavage of the anion radical‐formed by electron transfer to the excited fluoroketone‐is a fast