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Catalytic asymmetric reductive addition of olefins to aldehydes mediated by boron and zinc organometallics

✍ Scribed by Lothar Schwink; Paul Knochel


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
371 KB
Volume
35
Category
Article
ISSN
0040-4039

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3-Substituted BINOL Schiff bases and the
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## Abstract Three new chiral 3‐substituted BINOL Schiff bases and their reductive 3‐arylaminomethyl BINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active se