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Catalytic Asymmetric Oxidation of tert -Butyl Disulfide. Synthesis of tert -Butanesulfinamides, tert -Butyl Sulfoxides, and tert -Butanesulfinimines

✍ Scribed by Cogan, Derek A.; Liu, Guangcheng; Kim, Kyungjin; Backes, Bradley J.; Ellman, Jonathan A.

Book ID
118129901
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
259 KB
Volume
120
Category
Article
ISSN
0002-7863

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## Abstract Enantiomerically pure benzyl sulfoxides are effective tools for the formation of new C–C bonds with control of configuration at new stereogenic centres. The reaction of enantioenriched __tert__‐butyl __tert__‐butanethiosulfinate with benzyllithium derivatives, obtained by deprotonation