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Catalytic Asymmetric Hydrophosphonylation of Ketimines

✍ Scribed by Yin, Liang; Bao, Youmei; Kumagai, Naoya; Shibasaki, Masakatsu


Book ID
120557457
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
479 KB
Volume
135
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Catalytic Asymmetri
✍ Daisuke Uraguchi; Takaki Ito; Shinji Nakamura; Takashi Ooi πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 39 KB

## Abstract An enantioselective hydrophosphonylation of ynones (I) is achieved by exploiting the nucleophilicity of tetraaminophosphonium phosphite as well as the proton‐donating and stereocontrolling abilities of the chiral aminophosphonium cation.