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Catalytic Asymmetric Epoxidation of Aldehydes. Optimization, Mechanism, and Discovery of Stereoelectronic Control Involving a Combination of Anomeric and Cieplak Effects in Sulfur Ylide Epoxidations with Chiral 1,3-Oxathianes

✍ Scribed by Aggarwal, Varinder K.; Ford, J. Gair; Fonquerna, Sílvia; Adams, Harry; Jones, Ray V. H.; Fieldhouse, Robin

Book ID
120405028
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
517 KB
Volume
120
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Catalytic Asymmetric Epoxidation of Aldehydes. Optimization, Mechanism, and Discovery of Stereoelectronic Control Involving a Combination of Anomeric and Cieplak Effects in Sulfur Ylide Epoxidations with Chiral 1,3-Oxathianes.
✍ V. K. AGGARWAL; J. G. FORD; S. FONQUERNA; H. ADAMS; R. V. H. JONES; R. FIELDHOUS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

Catalytic Asymmetric Epoxidation of Aldehydes. Optimization, Mechanism, and Discovery of Stereoelectronic Control Involving a Combination of Anomeric and Cieplak Effects in Sulfur Ylide Epoxidations with Chiral 1,3-Oxathianes. -The chiral sulfide (CTH) is an efficient catalyst for the asymmetric epo