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Catalytic Asymmetric Conjugate Reactions (CORDOVA:ASYM CONJUG ADDIT O-BK) || Organocatalytic Enantioselective Conjugate Additions of Heteroatoms to α,βUnsaturated Carbonyl Compounds

✍ Scribed by Córdova, Armando

Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Year
2010
Tongue
German
Weight
295 KB
Edition
1
Category
Article
ISBN
3527324119

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Catalytic Asymmetric Conjugate Reactions
Catalytic Asymmetric Conjugate Reactions (CORDOVA:ASYM CONJUG ADDIT O-BK) || Asymmetric Epoxidations of α,β-Unsaturated Carbonyl Compounds
✍ Córdova, Armando 📂 Article 📅 2010 🏛 Wiley-VCH Verlag GmbH & Co. KGaA 🌐 German ⚖ 457 KB

Scheme 9.1 The Weitz-Scheffer epoxidation. alkenes requires the formation of nucleophilic oxidative species. The first example of the epoxidation of α,β-unsaturated carbonyl compounds was reported by Weitz and Scheffer in 1921 (Scheme 9.1) [16]. This two-step process first involves the conjugate a