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Catalytic Asymmetric Conjugate Reactions (CORDOVA:ASYM CONJUG ADDIT O-BK) || Catalytic Asymmetric Baylis-Hillman Reactions and Surroundings

✍ Scribed by Córdova, Armando


Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Year
2010
Tongue
German
Weight
577 KB
Edition
1
Category
Article
ISBN
3527324119

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✦ Synopsis


The Reaction Mechanism

Although the first arrow-pushing mechanism was reported by Hoffman and Rabe in 1986 [6], Hill and Isaacs [7] later proposed the commonly accepted mechanism Catalytic Asymmetric Conjugate Reactions.


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Catalytic Asymmetric Conjugate Reactions
✍ Córdova, Armando 📂 Article 📅 2010 🏛 Wiley-VCH Verlag GmbH & Co. KGaA 🌐 German ⚖ 103 KB 👁 1 views

All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or o

Catalytic Asymmetric Conjugate Reactions
✍ Córdova, Armando 📂 Article 📅 2010 🏛 Wiley-VCH Verlag GmbH & Co. KGaA 🌐 German ⚖ 457 KB 👁 1 views

Scheme 9.1 The Weitz-Scheffer epoxidation. alkenes requires the formation of nucleophilic oxidative species. The first example of the epoxidation of α,β-unsaturated carbonyl compounds was reported by Weitz and Scheffer in 1921 (Scheme 9.1) [16]. This two-step process first involves the conjugate a