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Catalytic Asymmetric Conjugate Addition of α-Cyanoketones for the Construction of a Quaternary Stereogenic Center

✍ Scribed by Kawato, Yuji; Takahashi, Noriko; Kumagai, Naoya; Shibasaki, Masakatsu


Book ID
121341597
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
602 KB
Volume
12
Category
Article
ISSN
1523-7060

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✍ Yuji Kawato; Noriko Takahashi; Naoya Kumagai; Masakatsu Shibasaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

## Abstract The addition of (hetero‐)aryl vinyl ketones to the cyclic cyanoketones provides 1,5‐dicarbonyl compounds with good to excellent yields and enantioselectivities with exception of alkyl vinyl ketone (IIa).