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Catalytic Asymmetric Carbohydroxylation of Alkenes by a Tandem Diboration/Suzuki Cross-Coupling/Oxidation Reaction.

✍ Scribed by Steven P. Miller; Jeremy B. Morgan; Felix J. V Nepveux; James P. Morken

Publisher: John Wiley and Sons
Year: 2004
Weight: 197 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200423034

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## Abstract Through the use of [PdCl(C~3~H~5~)]~2~/__cis__,__cis__,__cis__‐1,2,3,4‐tetrakis[(diphenylphosphanyl)methyl]cyclopentane as a catalyst, a range of vinyl bromides undergo Suzuki cross‐couplings with arylboronic acids in good yields. Furthermore, the catalyst can be used at low loadings, e