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Catalytic Asymmetric Aziridination with Borate Catalysts Derived from VANOL and VAPOL Ligands: Scope and Mechanistic Studies

✍ Scribed by Yu Zhang; Aman Desai; Zhenjie Lu; Gang Hu; Zhensheng Ding; William D. Wulff

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
523 KB
Volume
14
Category
Article
ISSN
0947-6539

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Catalytic Asymmetric Aziridination with
Catalytic Asymmetric Aziridination with Arylborate Catalysts Derived from VAPOL and VANOL Ligands
✍ Jon C. Antilla; William D. Wulff 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB 👁 1 views

The ring opening of chiral aziridines is a potent method for the synthesis of optically active amines. [1] The driving force of this process derives from the ring strain of the aziridine and this can be used to extend the ring opening to a variety of nucleophiles to produce difuncational amines with