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Catalytic Asymmetric Aza Diels—Alder Reactions of Hydrazones Using a Chiral Zirconium Catalyst.

✍ Scribed by Yasuhiro Yamashita; Yumiko Mizuki; Shu Kobayashi

Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ S. KOBAYASHI; S. KOMIYAMA; H. ISHITANI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

The First Enantioselective Aza-Diels-Alder Reactions of Imino Dienophiles on Use of a Chiral Zirconium Catalyst. -The first examples of catalytic, enantioselective DA reactions of imine dienophiles with Danishefsky's dienes are reported. The free hydroxyl group of the aldimines is crucial with resp