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Catalytic, Asymmetric Aza-Baylis–Hillman Reaction of N-Sulfonated Imines with Activated Olefins by Quinidine-Derived Chiral Amines

✍ Scribed by Min Shi; Yong-Mei Xu; Yong-Ling Shi

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
186 KB
Volume
11
Category
Article
ISSN
0947-6539

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Catalytic, Asymmetric Aza-Baylis—Hillman
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## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (