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Catalytic and Stoichiometrically Directed Synthesis of Less Accessible Bromothiophenes and Bromobithiophenes. Trapping and Characterization of Catalytic Intermediates of trans -PdBr(C 4 H 4- n Br n -1 S- C )(PPh 3 ) 2 ( n = 1−4), trans -PdBr(C 8 H 4 BrS 2 - C )(PPh 3 ) 2 , and trans , trans -Pd 2 Br 2 (μ-C 8 H 6- n Br n -2 S 2 - C , C ‘)(PPh 3 ) 4 ( n = 2, 4)

✍ Scribed by Xie, Yang; Wu, Bo-Mu; Xue, Feng; Ng, Siu-Choon; Mak, Thomas C. W.; Hor, T. S. Andy

Book ID
120411597
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
171 KB
Volume
17
Category
Article
ISSN
0276-7333

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ChemInform Abstract: Catalytic and Stoichiometrically Directed Synthesis of Less Accessible Bromothiophenes and Bromobithiophenes. Trapping and Characterization of Catalytic Intermediates of trans-PdBr(C4H4-nBrn-1S-C) (PPh3)2 (n = 1—4), trans-PdBr(C8H4BrS2-C) (PPh3)2, and trans,trans-Pd2Br2 (μ-C8H6-nBrn-2S2-C,C′) (PPh3)4 (n = 2, 4).
✍ Y. XIE; B.-M. WU; F. XUE; S.-C. NG; T. C. W. MAK; T. S. A. HOR 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 2 views

Catalytic and Stoichiometrically Directed Synthesis of Less Accessible Bromothiophenes and Bromobithiophenes. Trapping and Characterization of Catalytic Intermediates of trans-PdBr( C 4 H 4-n Br n-1 S-C) (PPh 3 ) 2 (n = 1-4), trans-PdBr(C 8 H 4 BrS 2 -C) (PPh 3 ) 2 , andtrans,trans-Pd 2 Br 2 -Isome