𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Catalytic and Stereoselective ortho -Lithiation of a Ferrocene Derivative

✍ Scribed by Steffen, Patricia; Unkelbach, Christian; Christmann, Mathias; Hiller, Wolf; Strohmann, Carsten


Book ID
120589389
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
821 KB
Volume
52
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


A Synthesis Detour to Planar-Diastereois
✍ Immo Weber; Frankβ€…W. Heinemann; Ulrich Zenneck πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 German βš– 255 KB

## Abstract Usually, __ortho__ lithiation of __Kagan__'s template **1** and quenching with electrophiles leads highly diastereoselectively to planar‐chiral 1,2‐disubstituted ferrocenes. Surprisingly, lithiation of **1** with lithium diisopropylamide (LDA) followed by addition of paraformaldehyde af