✍ Scribed by Sandra E Martı́n; Darı́o F Suárez
No coin nor oath required. For personal study only.
Selective aerobic oxidation of secondary and benzylic alcohols was efficiently accomplished by the binary catalyst system Fe(NO 3 ) 3 -FeBr 3 under air at room temperature. The oxidation developed in mild conditions and showed good yields. A secondary alcohol even in the presence of a primary one was selectively oxidized.
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The binary system Fe(NO 3 ) 3 -FeBr 3 is a very efficient catalyst for the selective air-oxidation of sulfides to sulfoxides. Since the oxidation is selective, it may be applied to any type of dialkyl and alkyl aryl sulfide, as well as to substrates of biological interest. It develops in mild condit
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