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Catalytic Activity of Rhodium-Siloxide Complexes in Hydrosilylation of Allyl Ethers and Allyl Esters

✍ Scribed by Bogdan Marciniec; Edyta Walczuk; Paulina Blazejewska-Chadyniak; Dariusz Chadyniak; Malgorzata Kujawa-Welten; Stanislaw Krompiec


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis and Catalytic Activity of η1-A
✍ Yutaka Matsuo; Takashi Uematsu; Eiichi Nakamura 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract η^1^‐Allyl and η^3^‐allyl, ethyl, and hydrido ruthenium complexes of pentamethyl[60]fullerene, Ru(η^5^‐C~60~Me~5~)R(CO)~2~(R = η^1^‐allyl, Et, H) and Ru(η^5^‐C~60~Me~5~)(η^3^‐allyl)(CO) were synthesized by the reaction of a chlorido complex Ru(η^5^‐C~60~Me~5~)Cl(CO)~2~ with an allyl and