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Catalytic Activity of Mesoporous Silica for Synthesis of MethylN-Phenyl Carbamate from Dimethyl Carbonate and Aniline

โœ Scribed by Naonobu Katada; Haruhisa Fujinaga; Yukinori Nakamura; Kazu Okumura; Kyoichi Nishigaki; Miki Niwa

Book ID
110336320
Publisher
Springer US
Year
2002
Tongue
English
Weight
266 KB
Volume
80
Category
Article
ISSN
1011-372X

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Direct synthesis of dimethyl carbonate f
Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over organotin-functionalized mesoporous benzene-silica
โœ Fan, Binbin (author);Li, Hongyu (author);Fan, Weibin (author);Qin, Zhangfen (aut ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› International Union of Pure and Applied Chemistry ๐ŸŒ English โš– 534 KB

Ordered periodic mesoporous benzene-silicas (Ph-PMOs) functionalized with organotin were synthesized by co-condensing (MeO)~2~ClSi(CH~2~)~3~SnCl~3~, tetraethyl orthosilicate (TEOS), and 1,4-bis(triethoxysilyl)-benzene in a Pluronic 123 acid solution. The diffraction lines for (100), (110), and (200)