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Catalytic activity and mechanism for the action of pyridines in the phenolysis of epichlorohydrin

✍ Scribed by I. V. Perepichka; E. N. Shved; Z. V. Stepanenko


Book ID
110544314
Publisher
Springer
Year
1999
Tongue
English
Weight
181 KB
Volume
35
Category
Article
ISSN
0040-5760

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Enhancing the Catalytic Activity of 4-(D
✍ Markus R. Heinrich; Heike Sabine Klisa; Herbert Mayr; Wolfgang Steglich; Hendrik πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 102 KB

Dedicated to Professor Heinrich NΓΆth on the occasion of his 75th birthday 4-(Dimethylamino)pyridine (DMAP, 1) was introduced to synthetic chemistry as a powerful nucleophilic group-transfer catalyst more than three decades ago [1,2] and has become a standard reagent [3] for acylation, esterification