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Catalytic activation of C–H bonds of alkanes, ethene and aromatic hydrocarbons by the adducts of active carbons with metallic potassium

✍ Scribed by S Rummel; S.M Yunusov; M.A Ilatovskaya; H Langguth; E.I Mysov; M Wahren; V.A Likholobov; V.B Shur

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 60 KB
Volume: 132
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(97)00247-1

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✦ Synopsis

It has been shown that the adducts of active carbons with metallic potassium are able to activate C-H bonds of alkanes, ethene and aromatic hydrocarbons and introduce these compounds into the hydrogen-deuterium exchange reactions at room temperature. This paper describes the reactions of the redistribution of hydrogen isotopes in CD H, C H CD and 3 6 5 3 C D CH catalysed by the potassium-carbon adducts as well as the similar isotope exchange reactions in the systems 6 5 3

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