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Catalyst dependent mechanistic paths in the reactions of ethyl diazoacetate with β-keto esters

✍ Scribed by Andrew C. Lottes; John A. Landgrebe; Kristin Larsen

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 208 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99330-4

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✦ Synopsis

The catalyzed decanpos ition of ethyl diazoacetati in the Presence of B-keto esters produces regioisaneric enol ethers and the diester fran formal carbenoid insertion into the a-C-H bond. The product distribution is very catalyst dependent.

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