Catalysis of the Reaction of Cholesteryl Acetate with 4-Phenyl-1,2,4-triazoline-3,5-dione by Lithium Perchlorate.
β Scribed by Wojciech J. Kinart; Ryszard B. Nazarski; Cezary M. Kinart; Quang T. Thuong; Rafal Oszczeda
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 14 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract Relative rates of [4 + 2] cycloadditions of cyclopentadienes 1aβ1e with 4βphenylβ1,2,4βtriazolineβ3,5βdione (2) in 12 different solvents vary by factors of up to 19000, but the reactions show similar solvent effects. Rate constants __k__~2~ correlate well with solvent parameters __AN__