Mechanistic Insights into the cisβtrans
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Dr. Albert Poater; Dr. Francesco Ragone; Dr. Andrea Correa; Dr. Anna Szadkowska;
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Article
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2010
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John Wiley and Sons
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English
β 647 KB
## Abstract The mechanism of the __trans__ to __cis__ isomerization in Ru complexes with a chelating alkylidene group has been investigated by using a combined theoretical and experimental approach. Static DFT calculations suggest that a concerted singleβstep mechanism is slightly favored over a mu