Catalysis of hydrosilylation: XXIII. Effect of substituents at silicon on unusual hydrosilylation of vinylsilanes catalysed by nickel acetylacetonate

Stereoelectronic effects of substituents

Stereoelectronic effects of substituents at silicon on the hydrosilylation of 1-hexene catalysed by [RhCl(cod)(1-hexene)]

✍ Wojciech Duczmal; Elzbieta Śliwińska; Beata Maciejewska; Bogdan Marciniec; Hiero 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 465 KB

Trisubstituted silanes, HSiR 3 \_,X, (R = Me or Et, X = C1, OEt, or Ph; n =0-3) oxidatively add to the complex [RhCl(cod . Subsequent steps of hydrosilylation follow, i.e. cis-insertion of the alkene (u-a rearrangement) and then reductive elimination of the product, according to the general Chalk a