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Catalysis of Friedel-Crafts Alkylation by a Montmorillonite Doped with Transition-Metal Cations

✍ Scribed by Pierre Laszlo; Arthur Mathy


Publisher
John Wiley and Sons
Year
1987
Tongue
German
Weight
522 KB
Volume
70
Category
Article
ISSN
0018-019X

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## Abstract An enantiospecific route towards bioactive merosesquiterpenes, based on the cationic‐resin‐promoted Friedel–Crafts alkylation of alkoxyarenes with an α,β‐unsaturated ketone, is reported. Reaction of ketone **11** with 3,4‐methylenedioxyphenol afforded the corresponding chromene. Treatme