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Catalysis in the reduction of plutonium (IV) by uranium (IV)

✍ Scribed by P. Biddle; J.H. Miles; M.J. Waterman


Book ID
118905940
Publisher
Elsevier Science
Year
1966
Weight
169 KB
Volume
28
Category
Article
ISSN
0022-1902

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phosphine oxidea can be reduced by triethoxysilane, or more cmvcniently polymetbylhydrosiloxane, and catalytic titamiu~~~ (IV) isopropoxide. and provides a system for the eftident one-pot generation of phosphonium salts; the reduction occurs with retention of configuration at phcx3phorus We recentl