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Catalysis in ester cleavage. III. Solvent isotope effects and transition-state solvation in the basic methanolysis of esters

โœ Scribed by Mitton, Carl G.; Gresser, Michael; Schowen, Richard L.


Book ID
121018541
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
366 KB
Volume
91
Category
Article
ISSN
0002-7863

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Calorimetric studies in solution solvent
โœ J.J.Moura Ramos; Marie-Louise Stien; J. Reisse ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 354 KB

TIP= relat.ivo salvation of the ground and the excited states corresponding to the n -L R\* W transition of carbonyl chromophores is determined, for a serie of solvents, on the basis of (11 the value of AE = hv, (2) the salvation enthaipy of the ground state determined by calorimetry, (3) the enthai