✦ LIBER ✦

Catalysis in aqueous solution: Hydrogenation of benzene derivatives catalysed by (η6-C6H6)2Ru2Cl4

✍ Scribed by Eva Garcia Fidalgo; Laurent Plasseraud; Georg Süss-Fink

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 169 KB
Volume: 132
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(97)00229-x

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✦ Synopsis

Ž 6 . The catalytic hydrogenation of various benzene derivatives was studied, using h -C H Ru Cl in aqueous solution as 6 6 2 2 4 1 h -C H Ru Cl precursor. An intermediate, presumably the more active species, was detected by H-NMR spectroscopy 6 6 2 2 4 w Ž 6 . Ž .Ž .Ž . x q under catalytic conditions and identified as the trinuclear cluster cation Ru h -C H m -Cl m -O m -H . q 1998 3 6 63 2 3 2 2 Elsevier Science B.V. All rights reserved.

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