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Catalysis by Oxide-Supported Clusters of Iridium and Rhodium: Hydrogenation of Ethene, Propene, and Toluene

โœ Scribed by Argo, A. M.; Odzak, J. F.; Goellner, J. F.; Lai, F. S.; Xiao, F.-S.; Gates, B. C.


Book ID
125478388
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
231 KB
Volume
110
Category
Article
ISSN
0022-3654

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Genesis of silica-supported [FesRhC(CO)t~]-and [Fe4RhC(CO)~4]-clusters with interstitial carbon atoms have been investigated in CO, syn-gas and Ar media. Complete conversion of the former cluster to the latter was obtained at 50ยฐC in any medium, with [Fe4RhC(CO)I4] cluster yielding Fe4Rh2C(CO)I 6 an