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Cassane-Type Diterpenoids from the Seeds of Caesalpinia magnifoliolata

✍ Scribed by Yinhua Yin; Lei Ma; Li-Hong Hu


Publisher
John Wiley and Sons
Year
2008
Tongue
German
Weight
206 KB
Volume
91
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Two novel cassane‐type diterpenes, named magnicaesalpin (1) and neocaesalpin O (2), together with three known compounds, caesalmin D (3), caesalmin E (4), and neocaesalpin L (5), were isolated from the MeOH extract of seeds of Caesalpinia magnifoliolata Metc. Their structures were determined by spectroscopic methods, (1D‐ and 2D‐NMR, HR‐EI‐MS) and X‐ray analysis, as well as by comparison of their spectral data with those of related compounds.


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ChemInform Abstract: Cassane-Type Diterp
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## Abstract A new dimer **1** and two new cassane‐type diterpenes **2** and **3**, designated taepeenin J–L, were isolated from the seeds of __Caesalpinia crista__ L. Compound **1** possesses a dimeric vouacapane skeleton. Their structures were elucidated on the basis of spectroscopic analysis.