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CASPT2 Study of Photodissociation Pathways of Ketene

โœ Scribed by Xiao, Hongyan; Maeda, Satoshi; Morokuma, Keiji


Book ID
119948688
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
418 KB
Volume
117
Category
Article
ISSN
1089-5639

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The infrared spectra of the n 2 / n 3 and n 2 / n 4 bands of ketene, from 3526 to 3538 cm 01 and from 3257 to 3277 cm 01 , respectively, have been obtained using an IR-UV double resonance photolysis scheme. A tunable IR laser pulse is followed by a UV photolysis pulse. When both an IR and a UV photo