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Cascade Reactions Using LiAlH4 and Grignard Reagents in the Presence of Water

✍ Scribed by M. Brett Runge; Martin T. Mwangi; A. Lee Miller II; Mathew Perring; Ned B. Bowden

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
341 KB
Volume
120
Category
Article
ISSN
0044-8249

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## Catalytic Dechlorination of Aromatic Chlorides Using Grignard Reagents in the Presence of (C 5 H 5 ) 2 TiCl 2 . -The dechlorination of alkyl chlorides is also attempted under similar conditions. Thus, 1-chlorooctane gives octane in a moderate yield of 64% and isomers of octenes are detected as