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Cars spectroscopy of gas phase CD3

✍ Scribed by James T. Miller; Katherine A. Burton; R.Bruce Weisman; Wen-Xue Wu; Paul S. Engel

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
422 KB
Volume
158
Category
Article
ISSN
0009-2614

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✦ Synopsis

Transient CARS spectroscopy has been used to study the Raman-active vI (symmetric C-D stretch) vibration-rotation band of CD, radicals formed by gas phase laser photolysis of azomethane-d,.

The following spectroscopic constants have been deduced: bandorigin=2157.5cm-',~=-0.026cm-',AC=-0.018cm-~,andX,,=-5cm-'.

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