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CARS probe of RDX decomposition

✍ Scribed by Kenneth Aron; L.E. Harris

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 448 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80331-0

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Comments on “CARS probe of RDX decomposi

Comments on “CARS probe of RDX decomposition”

✍ J.H. Stufflebeam; A.C. Eckbreth 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 92 KB

Rccenr CARS data from a solid propellant flame that purported to show resorunces from tile bcndina modes of HCN arc an;llyzud to dcmonstratc that the spectral features in question arc vibrational transitions of COz.

Reply to Comment on “CARS probe of RDX d

Reply to Comment on “CARS probe of RDX decomposition”

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Thermal decomposition of RDX and mixtures

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Thermal decomposition of pure cyclotrimethylene trinitramine (RDX) shows an endothermic peak at 205'C attributed to melting, followed by exothermic decomposition leading to a strong peak at 24O'C, and a very strong thermogravimetric peak at 260°C with a mass loss of 95%. However, the mixture of RDX,

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Mass spectrometric investigation of the thermal decomposition of RDX

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The products of thermal decomposition of 1,3,5trinitrohe~.d~dro 1,3,5trkzine (RDS) in vacuum hae been determined mass spectrometriczdly belo\\ and above the melting point. Employins a cell with an elongated orifice to form d collimated beam, RDS decomposition products acre identified M ithin 3 fea m

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The kinetics of the thermal decomposition of RDX and the formation of three nitroso intermediates have been studied in hexaproteo (h6) benzene; hexadeutero (d6) benzene at 180"C and 200"C; and, as a melt at 210°C in sealed capillaries. Decomposition rates were determined by vapor-phase chromatograph