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CARS in conformational analysis. Polarization CARS spectra of chlorocyclohexane

✍ Scribed by A. I. Fishman; A. E. Klimovitskii; A. I. Skvortsov


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
257 KB
Volume
28
Category
Article
ISSN
0377-0486

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✦ Synopsis


Polarization CARS (PCARS) spectroscopy was employed to study the Raman spectra of conformationally heterogeneous media. As an example, the Raman and PCARS spectra of chlorocyclohexane were investigated in the range 970-1020 cm-1. The analysis of these spectra showed the existence of three closely spaced bands and their spectral parameters were determined. 1997


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## Abstract The 220 MHz PMR spectrum of car‐3‐ene (3,7,7‐trimethylbicyclo[4,1,0]hept‐3‐ene) is interpreted and a conformation deduced. In contrast to previous work, which has discussed a highly buckled structure for the 6 membered ring, the present work finds this ring to be essentially planar.