Carrol rearrangement on the surface of chromatographic grade alumina

✍ Scribed by S.I. Pogrebnoi; Y.B. Kalyan; M.Z. Krimer; W.A. Smit

• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 274 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)96654-1

✦ Synopsis

Thermolysis on the surface of A1203 is proposed as a mild and convenient preparative method for /3,3/-sigmatropic Carrol rearrangement of acetoacetic esters of tertiary ally1 alcohols into respective )3&unsaturated ketones.