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Carboxylation of C−H Bonds Using N -Heterocyclic Carbene Gold(I) Complexes

✍ Scribed by Boogaerts, Ine I. F.; Nolan, Steven P.

Book ID
120049262
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
265 KB
Volume
132
Category
Article
ISSN
0002-7863

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__N__-Heterocyclic carbene (NHC) copper complexes serve as an excellent catalytic system for carboxylation of alkyl-, aryl-, and alkenylboron compounds and some aromatic heterocyclic C-H bonds with carbon dioxide (CO~2~), to afford various functional-group-containing carboxylic acids or their ester