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Carboxylates as Proton-Accepting Groups in Concerted Proton−Electron Transfers. Electrochemistry of the 2,5-Dicarboxylate 1,4-Hydrobenzoquinone/2,5-Dicarboxy 1,4-Benzoquinone Couple

✍ Scribed by Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel


Book ID
127297827
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
99 KB
Volume
128
Category
Article
ISSN
0002-7863

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## Abstract 1,2,3,4‐tetrachloro‐5,6,7,8‐tetrafluoro‐9‐methyltriptycene was studied in NMR spectra at low temperatures where the methyl group dynamics is frozen. Values of ^5^__J__(^19^F,^1^H), ^1^__J__(^13^C,^1^H), and ^2^__J__(^1^H,^1^H) for the individual methyl protons were measured. They are in